Acta Crystallographica Section E (Sep 2010)

[2-(sec-Butyliminomethyl)quinoline]chlorido(η6-1-isopropyl-4-methylbenzene)ruthenium(II) hexafluoridophosphate

  • José Luis Gárate-Morales,
  • Simón Hernández-Ortega,
  • Juan Manuel Fernández-G

DOI
https://doi.org/10.1107/S1600536810033003
Journal volume & issue
Vol. 66, no. 9
pp. m1147 – m1147

Abstract

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In the title compound, [RuCl(C10H14)(C14H16N2)]PF6, the aromatic ring of the isopropylmethylbenzene fragment shows an η6-arene coordination to the ruthenium atom. Its coordination sphere is completed by a chloride ligand and 2-(sec-butyliminomethyl)quinoline. The dihedral angle between the η6-arene ring and the quinoline Schiff base is 45.64 (9)°. The sec-butyl substituent and the PF6− anion are disordered over two positions with ratios of 0.595 (11):0.405 (11) and 0.752 (8):0.248 (8), respectively.