Acta Crystallographica Section E (Oct 2010)

[Benzyl(2-pyridylmethylidene)amine]dichloridomercury(II)

  • Sung Kwon Kang,
  • Young-Inn Kim

DOI
https://doi.org/10.1107/S1600536810035889
Journal volume & issue
Vol. 66, no. 10
pp. m1251 – m1251

Abstract

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The HgII ion in the title complex, [HgCl2(C13H12N2)], adopts a distorted tetrahedral geometry being coordinated by two Cl anions and by two N atoms of the benzyl(2-pyridylmethylene)amine ligand. The Cl—Hg—Cl plane is twisted at 70.1 (1)° from the mean plane of the chelate ring. In the crystal structure, intermolecular π–π interactions [centroid–centroid distance = 3.793 (3) Å] between the aromatic rings link the molecules into zigzag chains extending along [010].