Ammonium Pyrrolidine Dithiocarbamate-Modified CdTe/CdS Quantum Dots as a Turn-on Fluorescent Sensor for Detection of Trace Cadmium Ions

Abstract

In this work, ammonium pyrrolidine dithiocarbamate (APDC) was used as a surface etchant to modify CdTe/CdS core-shell quantum dots (QDs). The APDC etchant combines with the cadmium ions (Cd2+) on the surface of the QDs, resulting in the formation of surface holes. The formation of these holes changes the QD surface structure, which leads to fluorescence quenching of the QDs. Newly added Cd2+ can selectively recognize and combine with these holes; thus, the fluorescence intensity of the QDs can be restored. The linear response of this turn-on fluorescent sensor was found to be 0−100 μg/L and 100−600 μg/L under the determined optimal conditions, and its limit of detection (LOD) for Cd2+ was 2.642 μg/L (23.5 nmol/L).

Keywords

• quantum dot
• cadmium
• ammonium pyrrolidine dithiocarbamate
• fluorescence quenching
• fluorescent sensor