Investigation of the interactions and electromagnetic shielding properties of graphene oxide/platinum nanoparticle composites prepared under low-dose gamma irradiation

Abstract

Abstract A low-dose gamma irradiation was used for the one-step synthesis of graphene oxide/platinum nanoparticle composites. Various spectroscopic and microscopic methods were employed to structurally and morphologically characterize the prepared composites, and the nature of the interactions between graphene oxide sheets and platinum clusters was investigated using density function theory (DFT). Gamma irradiation caused the reduction of hexachloroplatinic acid, resulting in the formation of Pt nanoparticles and the simultaneous partial reduction of graphene oxide (GO). Pt nanoparticles synthesized at doses of 10 and 20 kGy showed a homogeneous GO surface coverage with a high portion of particles with sizes of up to 10 nm. The DFT results indicate a difference in electrical conductivity between GO and PtNPs. This could cause charge redistribution across the contact area, creating a conductive network at the interface that should enhance the EMI shielding capabilities of the composite. The shielding efficiency of the composites measured at the X band showed a blockage of 77% of the incident electromagnetic wave at a center frequency of 10 GHz. The composite prepared at a 20 kGy dose exhibited a greater contribution from a mismatch loss component, attributed to the improved electrical conductivity induced by irradiation.

Keywords

• Graphene oxide
• Platinum nanoparticles
• Composites
• Gamma irradiation
• Electromagnetic shielding
• Density functional theory