Acta Crystallographica Section E (Jun 2013)

2-(4-Chlorophenyl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole

  • Shaaban K. Mohamed,
  • Mehmet Akkurt,
  • Adel A. E. Marzouk,
  • Francisco Santoyo-Gonzalez,
  • Mahmoud A. A. Elremaily

DOI
https://doi.org/10.1107/S1600536813012592
Journal volume & issue
Vol. 69, no. 6
pp. o875 – o876

Abstract

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The title compound, C24H19ClN2, crystallizes with two independent molecules in the asymmetric unit. The prop-2-enyl substituents on the imidazole rings adopt similar conformations in the two molecules. The 4-and 5-substituted phenyl rings and the benzene ring make dihedral angles of 67.06 (8), 5.61 (8) and 41.09 (8)°, respectively, with the imadazole ring in one molecule and 71.53 (8), 28.85 (8) and 41.87 (8)°, respectively, in the other. The crystal structure features C—H...π interactions and weak π–π stacking interactions [centroid–centroid distances = 3.6937 (10) and 4.0232 (10) Å] between the chlorophenyl rings, which form a three-dimensional supramolecular structure.