Journal of Chemistry (Jan 2017)

Application of Spent Li-Ion Batteries Cathode in Methylene Blue Dye Discoloration

  • Eric M. Garcia,
  • Hosane A. Taroco,
  • Ana Paula C. Madeira,
  • Amauri G. Souza,
  • Rafael R. A. Silva,
  • Júlio O. F. Melo,
  • Cristiane G. Taroco,
  • Quele C. P. Teixeira

DOI
https://doi.org/10.1155/2017/3621084
Journal volume & issue
Vol. 2017

Abstract

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This paper aims to present the mechanism study of methylene blue (MB) discoloration using spent Li-ion battery cathode tape and hydrogen peroxide. The recycled cathode used in this work is composed of 72% of LiCoO2, 18% of carbon, and 10% of Al. The value found for surface area is 8.9 m2/g and the ZCP value occurs in pH = 2.95. Different from what is proposed in the literature, the most likely mechanism of methylene blue discoloration is the oxidation/delitiation of LiCoO2 and the reduction of H2O2 forming OH∙. Thus, in this paper, an important and promising alternative for discoloration of textile industry dyes using spent Li-ion battery cathode is presented.