Acta Crystallographica Section E (Dec 2012)

(E)-tert-Butyl 4-(N′-hydroxycarbamimidoyl)piperazine-1-carboxylate

  • S. Sreenivasa,
  • K. E. Manojkumar,
  • P. A. Suchetan,
  • N. R. Mohan,
  • B. S. Palakshamurthy

DOI
https://doi.org/10.1107/S1600536812046223
Journal volume & issue
Vol. 68, no. 12
pp. o3347 – o3347

Abstract

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In the title compound, C10H20N4O3, the piperazine ring adopts a chair conformation. The molecule adopts an E conformation across the C=N double bond, with the –OH group and the piperazine ring trans to one another. Further, the H atom of the hydroxy group is directed away from the NH2 group. An intramolecular N—H...O contact occurs involving the NH2 group and the oxime O atom. In the crystal, molecules are linked via strong N—H...O and O—H...N hydrogen bonds with alternating R22(6) and C(9) motifs into tetrameric units forming R44(28) motifs.