Natural Forsterite Strongly Enriched in Boron: Crystal Structure and Spectroscopy

Abstract

Boron is a typical crustal element and largely incompatible in olivine. Most natural olivine samples have very low concentrations of boron. Recently, forsterite with high boron content (up to 60.53 wt% MgO and 1795.91 ppm B) has been discovered in the Jian forsterite jade in the Jian area of northeast China. In this study, B-rich forsterite was examined by electron microprobes, Laser Ablation-Inductively Coupled Plasma Mass Spectrometry, Single crystal X-ray diffraction, Raman spectroscopy, and infrared spectroscopy. The B-rich forsterite is orthorhombic, existing in space group Pnma, and its unit-cell parameters are: a = 10.1918(7) Å, b = 5.9689(4) Å, c = 4.7484(3) Å, α = 90°, β = 90°, γ = 90°, and V = 288.86(3) Å3. The results of single crystal X-ray diffraction analysis indicate that the unit-cell parameters (a, b, and c) and unit-cell volume of forsterite in Jian forsterite jade are much smaller than those of known olivine. An equivalent set of Raman and infrared spectra were measured for the natural B-rich forsterite and compared to the results for mantle forsterite with a Fo value of ~91. The Raman spectrum of B-rich forsterite is similar to that of mantle olivine. We conclude that the systematic peak position shifts towards higher Raman shift with increasing Fo content. The infrared spectrum of B-rich forsterite crystals is characterized by strong absorption bands at 761, 1168, 1259, and 1303 cm−1, which are assigned to stretching vibrations of BO3 groups. Our data further confirm the existence of the B(F, OH)Si–1O–1 coupled substitution in natural B-rich forsterite.

Keywords

• forsterite
• boron
• crystal structure
• spectroscopy