Nanomaterials (Jun 2022)

Self-Assembly Vertical Graphene-Based MoO<sub>3</sub> Nanosheets for High Performance Supercapacitors

  • Ao Cheng,
  • Yan Shen,
  • Tianzeng Hong,
  • Runze Zhan,
  • Enzi Chen,
  • Zengrui Chen,
  • Guowang Chen,
  • Muyuan Liang,
  • Xin Sun,
  • Donghang Wang,
  • Linchen Xu,
  • Yu Zhang,
  • Shaozhi Deng

DOI
https://doi.org/10.3390/nano12122057
Journal volume & issue
Vol. 12, no. 12
p. 2057

Abstract

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Supercapacitors have been extensively studied due to their advantages of fast-charging and discharging, high-power density, long-cycling life, low cost, etc. Exploring novel nanomaterial schemes for high-performance electrode materials is of great significance. Herein, a strategy to combine vertical graphene (VG) with MoO3 nanosheets to form a composite VG/MoO3 nanostructure is proposed. VGs as transition layers supply rich active sites for the growth of MoO3 nanosheets with increasing specific surface areas. The VG transition layer further improves the electric contact and adhesion of the MoO3 electrode, simultaneously stabilizing its volume and crystal structure during repeated redox reactions. Thus, the prepared VG/MoO3 nanosheets have been demonstrated to exhibit excellent electrochemical properties, such as high reversible capacitance, better cycling performance, and high-rate capability.

Keywords