The importance of organic carbon as a coadjutant in the transport of pollutants

Abstract

Dissolved organic carbon (DOC) is a physicochemical parameter widely used in the evaluation of surface water quality; however, its role as an agent of transport and transference of pollutants sometimes is still disregarded. The heterogeneous composition of DOC, predominantly composed of humin, humic and fulvic acids, renders it an inherent capacity to bind to organic and inorganic pollutants. This is an important feature when the knowledge of present and future conditions of aquatic environments is of concern. Some authors concluded that DOC is a controlling agent of mobility of metals, phosphorus, herbicides, and pesticides, among others. Nevertheless, some physical and chemical conditions in the water column and in the sediment can immobilize the contaminants and make the DOC less soluble, which will hamper the formation of DOC-pollutant complexes. This mini review is intended to present the importance of DOC quantification and some information on its association with water contaminants, which could render them unavailable for uptake. HIGHLIGHTS Dissolved organic carbon represents an important role in the dynamics of pollutants in water bodies.; There is a close relationship between the DOC and a pollutant in surficial sediments and pore water.; The heterogeneity of DOC composition turns it into a versatile ligand in aquatic systems.;

Keywords

• aquatic systems
• bed sediment
• dissolved organic carbon
• dynamics of pollutants
• mini-review
• organic matter