Comparative Study of Three Carbon Additives: Carbon Nanotubes, Graphene, and Fullerene-C60, for Synthesizing Enhanced Polymer Nanocomposites

Abstract

While nanoparticles from the carbon family have been incorporated effectively for polymer matrixes, there is no clear information available for understanding the impacts of the morphology of different carbon nanoparticles on the performance of carbon-based nanocomposites. Therefore, this study aimed to provide a comprehensive, comparative investigation to systematically assess the impacts of nanoparticles on the tribological, mechanical, and electrochemical properties of the epoxy coatings using three representative 0D, 1D, and 2D nanoparticles: Fullerene-C60 (C60), graphene nanoplatelets (GNPs), and carbon nanotubes (CNTs). The anti-corrosion performance of the nanocomposites in both the short and long term was characterized. The mechanical properties were examined by abrasion, adhesion, and tensile tests. Fourier-transform infrared spectroscopy (FTIR) was conducted to determine their chemical structures, while scanning electron microscopy (SEM) was used to determine their surface texture. The electrochemical impedance spectroscopy (EIS) results revealed that the coatings reinforced by C60 and GNP had better anti-corrosion performance than that of the CNT/epoxy samples. The incorporation of C60 and CNT led to a considerable improvement in tensile properties, while improved abrasion resistance was observed in all types of nanofiller/epoxy groups. C60-loaded composites exhibited a significant enhancement in tensile properties as compared to CNT or GNP composites.

Keywords

• nano-modified coating
• nanocomposite
• graphene nanoplatelets
• carbon nanotube
• fullerene-C60
• corrosion resistance