A Study on the Effect of Different Ball Milling Methods on the NH₃-SCR Activity of Aluminum-Laden Bayan Obo Tailings

Abstract

Rich in Fe, Ce, Mn, Si and other elements which have good catalytic activity, Bayan Obo rare-earth tailings are naturally advantaged as the carrier of denitrification catalysts. In this paper, pseudo boehmite (γ-Al2O3) was mixed with Bayan Obo tailings using different ball milling methods for modification to prepare NH3-SCR catalysts. The effect of different mixing methods on the SCR denitrification activity at a low temperature was investigated and the prepared catalysts were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), temperature programed desorption (NH3-TPD), temperature programed reduction (H2-TPR) and other means. The conversion rate of NOx at 250–350 °C was above 80% and the highest conversion rate of NOx of 90% was achieved at 300 °C. SEM and XRD revealed that the tailings modified by pseudo boehmite (γ-Al2O3) using the ordinary ball milling method have loose structure and good dispersion of active substances, and specific surface area (BET) analysis shows that the tailings have the maximum specific surface area and pore volume. However, over grinding and secondary spheronization were observed in the tailings modified by pseudo boehmite (γ-Al2O3) using high energy ball milling method, leading to the decrease of specific surface area and pore volume, poor dispersion of active substances, and ultimately low denitrification rate.

Keywords

• rare-earth tailings
• carrier
• pseudo boehmite
• ball milling
• NH₃-SCR activity