Theoretical Study of the Multiferroic Properties of Ion-Doped CaBaCo₄O₇

Abstract

Using a microscopic model and Green’s function theory, we investigated the magnetization, specific heat, and polarization properties of CaBaCo4O7 (CBCO), scrutinizing their variations with temperature, magnetic field strength, and doping effects. Our analysis revealed a conspicuous kink in the specific heat curve near the critical temperature (TC), indicative of a phase transition. Additionally, the observed increase in polarization, P with escalating magnetic field strength serves as compelling evidence for the multiferroic nature of CBCO. Substituting Co ions with Fe ions resulted in an augmentation of the CBCO magnetization, M, while doping with Zn, Mn, or Ni ions led to a decline. Similarly, doping CBCO with Y or Sr ions at the Ca site exhibited divergent effects on magnetization, M, with an increase in the former and a decrease in the latter case. This modulation of the magnetization, M, can be attributed to the varying strains induced by the doping ions, thereby altering the exchange interaction constants within the system. The polarization, P, increases by Ni, Mn, or Zn substitution on the kagome layer Co sites. It can be concluded that Ni, Mn, or Zn doping enhances the magnetoelectric effect of CBCO. Notably, our findings align qualitatively well with experimental observations, reinforcing the validity of our theoretical framework.

Keywords

• CaBaCo₄O₇
• ion doping
• magnetization
• specific heat
• polarization
• microscopic model