Acta Crystallographica Section E (Dec 2011)

Pentacarbonyl-1κ2C,2κ3C-(4-iodophenyl isocyanide-1κC)(μ-propane-1,3-dithiolato-1:2κ4S,S′:S,S′)iron(I)(Fe—Fe)

  • Jinli Zhu,
  • Yanfeng Tang,
  • Guo -Min Jiang,
  • Miao Wang,
  • Ping Hua

DOI
https://doi.org/10.1107/S1600536811047088
Journal volume & issue
Vol. 67, no. 12
pp. m1753 – m1754

Abstract

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In the title compound, [Fe2(C7H4IN)(C3H6S2)(CO)5], the Fe—Fe distance of 2.5156 (11) Å compares well with that in related model structures. The phenyl isocyanide ligand is in the basal position and trans to the S atoms of the propanedithiolate ligand due to steric hindrance. The crystal structure features C—H...O interactions.