Engineering Surface Properties of CuO/Ce_0.6Zr_0.4O₂ Catalysts for Efficient Low-Temperature Toluene Oxidation

Abstract

The development of superior low-temperature catalytic performance and inexpensive catalysts for the removal of volatile organic compounds (VOCs) is crucial for their industrial application. Herein, CuO/Ce0.6Zr0.4O2 catalysts calcinated at different temperatures (Cu/CZ-X, X represented calcination temperature) were prepared and used to eliminate toluene. It can be found that Cu/CZ-550 presented the highest low-temperature catalytic activity, with the lowest temperature (220 °C) 50% conversion of toluene, the highest normalized reaction rate (3.1 × 10−5 mol·g−1·s−1 at 180 °C) and the lowest apparent activation energy value (86.3 ± 4.7 kJ·mol−1). Systematically, the surface properties analysis results showed that the optimum redox property, abundant oxygen vacancies, and plentiful surface Ce3+ species over Cu/CZ-550 were associated with the strong interaction between Cu and support could significantly favor the adsorption and activation of toluene, thus resulting in its superior catalytic performance.

Keywords

• toluene oxidation
• copper-based catalyst
• surface property