Poly[(μ4-tetrazole-1-acetato-κ4N3:N4:O:O′)silver(I)]

Abstract

In the title complex, [Ag(C3H3N4O2)]n, the AgI atom is four-coordinated in a slightly distorted tetrahedral coordination geometry by two N atoms from two tetrazole-1-acetate (tza) ligands and two O atoms from the other two tza ligands. The tza ligand bridges two Ag atoms through the carboxylate O atoms and simultaneously binds to the other two Ag atoms through the tetrazole N atoms, forming a two-dimensional network parallel to (100).