Transient Effects in Fischer-Tropsch Reactor with a Fixed Bed of Catalyst Particles

Abstract

Based on analysis of small temperature disturbances in the Fischer-Tropsch reactor with a fixed bed of catalyst particles various scenarios of thermal instability were investigated. There are two possible scenarios of thermal instability of the reactor. First, thermal explosion may occur due to growth of temperature disturbances inside a catalytic granule. Second scenario connected with loss of thermal stability as a result of an initial increase in temperature in the reactor volume. The boundaries of thermal stability of the reactor were estimated by solving the eigenvalue problems for spherical catalyst particles and cylindrical reactor. Processes of diffusional resistance inside the catalytic granule and heat transfer from wall of the reactor tube are taken into account. Estimation of thermal stability area is compared with the results of numerical simulation of behavior of temperature and concentration of synthesis gas.DOI: 10.7463/mathm.0115.0777093

Keywords

• fischer-tropsch synthesis
• catalytic reactions
• diffusion resistance
• small disturbances
• the eigenvalue problem