Acta Crystallographica Section E (Nov 2011)
1,3-Bis(2-methoxyphenyl)thiourea
Abstract
In the title compound, C15H16N2O2S, the N–C(=S) bond lengths are indicative of the presence of amide-type resonance. The dihedral angles between the thiourea unit and the attached aromatic rings are 59.80 (5) and 73.41 (4)° while the dihedral angle between the rings is 56.83 (4)°. In the crystal, inversion dimers linked by pairs of N—H...S hydrogen bonds occur. An N—H...π interaction is observed for the second amino group. The shortest centroid–centroid distance between two aromatic systems is 4.0958 (8) Å.