Nature Communications (May 2023)

A quinary WTaCrVHf nanocrystalline refractory high-entropy alloy withholding extreme irradiation environments

  • O. El Atwani,
  • H. T. Vo,
  • M. A. Tunes,
  • C. Lee,
  • A. Alvarado,
  • N. Krienke,
  • J. D. Poplawsky,
  • A. A. Kohnert,
  • J. Gigax,
  • W.-Y. Chen,
  • M. Li,
  • Y. Q. Wang,
  • J. S. Wróbel,
  • D. Nguyen-Manh,
  • J. K. S. Baldwin,
  • O. U. Tukac,
  • E. Aydogan,
  • S. Fensin,
  • E. Martinez

DOI
https://doi.org/10.1038/s41467-023-38000-y
Journal volume & issue
Vol. 14, no. 1
pp. 1 – 12

Abstract

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Abstract In the quest of new materials that can withstand severe irradiation and mechanical extremes for advanced applications (e.g. fission & fusion reactors, space applications, etc.), design, prediction and control of advanced materials beyond current material designs become paramount. Here, through a combined experimental and simulation methodology, we design a nanocrystalline refractory high entropy alloy (RHEA) system. Compositions assessed under extreme environments and in situ electron-microscopy reveal both high thermal stability and radiation resistance. We observe grain refinement under heavy ion irradiation and resistance to dual-beam irradiation and helium implantation in the form of low defect generation and evolution, as well as no detectable grain growth. The experimental and modeling results—showing a good agreement—can be applied to design and rapidly assess other alloys subjected to extreme environmental conditions.