Silkworm Protein-Derived Nitrogen-Doped Carbon-Coated Li[Ni<sub>0.8</sub>Co<sub>0.15</sub>Al<sub>0.05</sub>]O<sub>2</sub> for Lithium-Ion Batteries
Gyu Sang Sim,
Nitheesha Shaji,
P. Santhoshkumar,
Jae Woo Park,
Chang Won Ho,
Murugan Nanthagopal,
Hong Ki Kim,
Chang Woo Lee
Affiliations
Gyu Sang Sim
Department of Chemical Engineering (Integrated Engineering), College of Engineering, Kyung Hee University, 1732 Deogyeong-daero, Giheung, Yongin 17104, Gyeonggi, Korea
Nitheesha Shaji
Department of Chemical Engineering (Integrated Engineering), College of Engineering, Kyung Hee University, 1732 Deogyeong-daero, Giheung, Yongin 17104, Gyeonggi, Korea
P. Santhoshkumar
Center for the SMART Energy Platform, College of Engineering, Kyung Hee University, 1732 Deogyeong-daero, Giheung, Yongin 17104, Gyeonggi, Korea
Jae Woo Park
Department of Chemical Engineering (Integrated Engineering), College of Engineering, Kyung Hee University, 1732 Deogyeong-daero, Giheung, Yongin 17104, Gyeonggi, Korea
Chang Won Ho
Department of Chemical Engineering (Integrated Engineering), College of Engineering, Kyung Hee University, 1732 Deogyeong-daero, Giheung, Yongin 17104, Gyeonggi, Korea
Murugan Nanthagopal
Department of Chemical Engineering (Integrated Engineering), College of Engineering, Kyung Hee University, 1732 Deogyeong-daero, Giheung, Yongin 17104, Gyeonggi, Korea
Hong Ki Kim
Department of Chemical Engineering (Integrated Engineering), College of Engineering, Kyung Hee University, 1732 Deogyeong-daero, Giheung, Yongin 17104, Gyeonggi, Korea
Chang Woo Lee
Department of Chemical Engineering (Integrated Engineering), College of Engineering, Kyung Hee University, 1732 Deogyeong-daero, Giheung, Yongin 17104, Gyeonggi, Korea
Li[Ni0.8Co0.15Al0.05]O2 (NCA) is a cathode material for lithium-ion batteries and has high power density and capacity. However, this material has disadvantages such as structural instability and short lifespan. To address these issues, herein, we explore the impact of N-doped carbon wrapping on NCA. Sericin, an easily obtained carbon- and nitrogen-rich component of silk cocoons, is utilized as the precursor material. The electrochemical performance evaluation of N-doped carbon-coated NCA shows that the capacity retention of 0.3 NC@NCA at 1C current density is 69.83% after 200 cycles, which is about 19% higher than the 50.65% capacity retention of bare NCA. The results reveal that the sericin-resultant N-doped carbon surface wrapping improves the cycling stability of NC@NCA.
