Acta Crystallographica Section E (Dec 2010)

(R)-[1-(2-Chlorophenyl)-2-methoxy-2-oxoethyl][2-(thiophen-2-yl)ethyl]ammonium (+)-camphor-10-sulfonate acetone monosolvate

  • Deng-Ke Liu,
  • Ying Liu,
  • Shuai Mu,
  • Yan-Shu Liang

DOI
https://doi.org/10.1107/S160053681004523X
Journal volume & issue
Vol. 66, no. 12
pp. o3117 – o3117

Abstract

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The title compound, C15H17ClNO2S+·C10H15O4S−·C3H6O, was synthesized by N-alkylation of α-amino-(2-chlorophenyl)acetate with 2-thienylethyl p-toluenesulfonate, followed by reaction with (+)-camphor-10-sulfonic acid. In the crystal, the cations and anions are linked through N—H...O hydrogen bonds. The thiophene ring of the cation was found to be disordered over two sites, with refined occupancies of 0.798 (4) and 0.202 (4).