Inorganics (Jun 2023)

Hydrogen Release and Uptake of MgH<sub>2</sub> Modified by Ti<sub>3</sub>CN MXene

  • Xiantun Huang,
  • Chenglin Lu,
  • Yun Li,
  • Haimei Tang,
  • Xingqing Duan,
  • Kuikui Wang,
  • Haizhen Liu

DOI
https://doi.org/10.3390/inorganics11060243
Journal volume & issue
Vol. 11, no. 6
p. 243

Abstract

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MgH2 has a high hydrogen content of 7.6 wt% and possesses good reversibility under normal conditions. However, pristine MgH2 requires a high temperature above 300 °C to release hydrogen, with very slow kinetics. In this work, we utilized Ti3CN MXene to reduce the operating temperature and enhance the kinetics of MgH2. The initial temperature of MgH2 decomposition can be lowered from 322 °C for pristine MgH2 to 214 °C through the employment of Ti3CN. The desorbed MgH2 + 7.5 wt% Ti3CN can start absorption at room temperature, while the desorbed pristine MgH2 can only start absorption at 120 °C. The employment of Ti3CN can significantly improve the hydrogen release kinetics of MgH2, with the desorption activation energy decreasing from 121 to 80 kJ mol−1. Regarding thermodynamics, the desorption enthalpy changes of MgH2 and MgH2 + 7.5 wt% Ti3CN were 79.3 and 78.8 kJ mol−1, respectively. This indicates that the employment of Ti3CN does not alter the thermal stability of MgH2. Phase evolution studies through the use of X-ray diffraction and electron diffraction both confirm that Ti3CN remains stable during the hydrogen release and uptake process of the composite. This work will help understand the impact of a transition metal carbonitride on the hydrogen storage of MgH2.

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