Crystals (Mar 2019)

Impact of Weak Nanoparticle Induced Disorder on Nematic Ordering

  • Dejvid Črešnar,
  • Christina Kyrou,
  • Ioannis Lelidis,
  • Aleksandra Drozd-Rzoska,
  • Szymon Starzonek,
  • Sylwester Janusz Rzoska,
  • Zdravko Kutnjak,
  • Samo Kralj

DOI
https://doi.org/10.3390/cryst9030171
Journal volume & issue
Vol. 9, no. 3
p. 171

Abstract

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Dilute mixtures of nanoparticles (NPs) and nematic liquid crystals (LCs) are considered. We focus on cases where NPs enforce a relatively weak disorder to the LC host. We use a Lebwohl-Lasher semi-microscopic-type modeling where we assume that NPs effectively act as a spatially-dependent external field on nematic spins. The orientational distribution of locally favoured “easy„ orientations is described by a probabilistic distribution function P. By means of a mean field-type approach, we derive a self-consistent equation for the average degree of nematic uniaxial order parameter S as a function of the concentration p of NPs, NP-LC coupling strength and P. Using a simple step-like probability distribution shape, we obtain the S(p) dependence displaying a crossover behaviour between two different regimes which is in line with recent experimental observations. We also discuss a possible origin of commonly observed non-monotonous variations of the nematic-isotropic phase temperature coexistence width on varying p.

Keywords