Nature Communications (Oct 2017)

A broadly tunable synthesis of linear α-olefins

  • Andreas Gollwitzer,
  • Thomas Dietel,
  • Winfried P. Kretschmer,
  • Rhett Kempe

DOI
https://doi.org/10.1038/s41467-017-01507-2
Journal volume & issue
Vol. 8, no. 1
pp. 1 – 6

Abstract

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Linear α-olefins are important bulk chemicals annually produced in megaton scale. Here, the authors report a trimetallic catalyst system for the synthesis of 1-butene and a broad range of α-olefins and achieve control over chain length by tuning the reaction rates of the nickel and yttrium catalysts.