Energies (Apr 2017)

Thermal Properties of Biochars Derived from Waste Biomass Generated by Agricultural and Forestry Sectors

  • Xing Yang,
  • Hailong Wang,
  • Peter James Strong,
  • Song Xu,
  • Shujuan Liu,
  • Kouping Lu,
  • Kuichuan Sheng,
  • Jia Guo,
  • Lei Che,
  • Lizhi He,
  • Yong Sik Ok,
  • Guodong Yuan,
  • Ying Shen,
  • Xin Chen

DOI
https://doi.org/10.3390/en10040469
Journal volume & issue
Vol. 10, no. 4
p. 469

Abstract

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Waste residues produced by agricultural and forestry industries can generate energy and are regarded as a promising source of sustainable fuels. Pyrolysis, where waste biomass is heated under low-oxygen conditions, has recently attracted attention as a means to add value to these residues. The material is carbonized and yields a solid product known as biochar. In this study, eight types of biomass were evaluated for their suitability as raw material to produce biochar. Material was pyrolyzed at either 350 °C or 500 °C and changes in ash content, volatile solids, fixed carbon, higher heating value (HHV) and yield were assessed. For pyrolysis at 350 °C, significant correlations (p < 0.01) between the biochars’ ash and fixed carbon content and their HHVs were observed. Masson pine wood and Chinese fir wood biochars pyrolyzed at 350 °C and the bamboo sawdust biochar pyrolyzed at 500 °C were suitable for direct use in fuel applications, as reflected by their higher HHVs, higher energy density, greater fixed carbon and lower ash contents. Rice straw was a poor substrate as the resultant biochar contained less than 60% fixed carbon and a relatively low HHV. Of the suitable residues, carbonization via pyrolysis is a promising technology to add value to pecan shells and Miscanthus.

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