Nature Communications (Jul 2019)

Atomic-scale engineering of indium oxide promotion by palladium for methanol production via CO2 hydrogenation

  • Matthias S. Frei,
  • Cecilia Mondelli,
  • Rodrigo García-Muelas,
  • Klara S. Kley,
  • Begoña Puértolas,
  • Núria López,
  • Olga V. Safonova,
  • Joseph A. Stewart,
  • Daniel Curulla Ferré,
  • Javier Pérez-Ramírez

DOI
https://doi.org/10.1038/s41467-019-11349-9
Journal volume & issue
Vol. 10, no. 1
pp. 1 – 11

Abstract

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Generating and quantifying the effect of the promoter speciation in heterogeneous catalysts is very challenging. Here, the authors show that the precise palladium atoms architecture reached by controlled co-precipitation overcomes selectivity and stability limitations associated with palladium nanoparticles for CO2-based methanol synthesis.