Correlation between Slow Magnetic Relaxations and Molecular Structures of Dy(III) Complexes with <em>N</em>₅<em>O</em>₄ Nona-Coordination

Abstract

A series of Dy(III) mononuclear complexes [DyA2L]+ (L denotes Schiff base N5 ligand that occupies equatorial positions and A− denotes bidentate anionic O-donor ligands such as NO3− (1), AcO− (2), and acac− (3)) were synthesized to investigate the correlation between the slow magnetic relaxation phenomena and the coordination structures around Dy(III). The Dy(III) ion in each complex is in a nona-coordination with the anionic O-donor ligand occupying up- and down-side positions of the N5 equatorial plane. 2 and 3 show slow magnetic relaxation phenomena under a zero bias-field condition, and all complexes showed slow magnetic relaxation under the applied 1000-Oe bias-field conditions. Arrhenius analyses revealed that the ΔE/kB, the barrier height for magnetization flipping, increases in this order, with the values of 24.1(6), 85(3), and 140(15) K. The effects of the exchanging axial ligands on the magnetic anisotropy were discussed together with the DFT calculations.

Keywords

• lanthanide complex
• slow magnetic relaxation
• single-molecule magnet
• crystal structure
• AC susceptibility
• DFT calculation