From Citrus Waste to Valuable Resources: A Biorefinery Approach
Nancy Medina-Herrera,
Guillermo Cristian Guadalupe Martínez-Ávila,
Claudia Lizeth Robledo-Jiménez,
Romeo Rojas,
Bianca Sherlyn Orozco-Zamora
Affiliations
Nancy Medina-Herrera
Laboratory of Chemistry and Biochemistry, School of Agronomy, Autonomous University of Nuevo Leon, v. Francisco Villa S/N, Ex Hacienda El Canadá, General Escobedo 66050, Mexico
Guillermo Cristian Guadalupe Martínez-Ávila
Laboratory of Chemistry and Biochemistry, School of Agronomy, Autonomous University of Nuevo Leon, v. Francisco Villa S/N, Ex Hacienda El Canadá, General Escobedo 66050, Mexico
Claudia Lizeth Robledo-Jiménez
Laboratory of Chemistry and Biochemistry, School of Agronomy, Autonomous University of Nuevo Leon, v. Francisco Villa S/N, Ex Hacienda El Canadá, General Escobedo 66050, Mexico
Romeo Rojas
Laboratory of Chemistry and Biochemistry, School of Agronomy, Autonomous University of Nuevo Leon, v. Francisco Villa S/N, Ex Hacienda El Canadá, General Escobedo 66050, Mexico
Bianca Sherlyn Orozco-Zamora
Laboratory of Chemistry and Biochemistry, School of Agronomy, Autonomous University of Nuevo Leon, v. Francisco Villa S/N, Ex Hacienda El Canadá, General Escobedo 66050, Mexico
Typically, citrus waste is composted on land by producers or used as livestock feed. However, the biorefinery approach offers a sustainable and economically viable solution for managing and valorizing these agricultural residues. This review examines research from the period 2014 to 2024. Citrus waste can be utilized initially by extracting the present phytochemicals and subsequently by producing value-added products using it as a raw material. The phytochemicals reported as extracted include essential oils (primarily limonene), pectin, polyphenolic components, micro- and nano-cellulose, proteins, and enzymes, among others. The components produced from the waste include bioethanol, biogas, volatile acids, biodiesel, microbial enzymes, and levulinic acid, among others. The review indicates that citrus waste has technical, economic, and environmental potential for utilization at the laboratory scale and, in some cases, at the pilot scale. However, research on refining pathways, optimization, and scalability must continue to be an active field of investigation.