Acta Crystallographica Section E (Dec 2011)

Guanidinium 2-(myristoylsulfanyl)ethanesulfonate

  • Elizabeth S. Monillas,
  • Wesley H. Monillas,
  • Eric R. Sirianni,
  • Glenn P. A. Yap,
  • Klaus H. Theopold

DOI
https://doi.org/10.1107/S1600536811046472
Journal volume & issue
Vol. 67, no. 12
pp. o3257 – o3257

Abstract

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In the title compound, CH6N3+·C16H31O4S2− [systematic name: guanidinium 2-(tetradecanoylsulfanyl)ethanesulfonate], each 2-(myristoylthio)ethanesulfonate ion displays hydrogen bonding to three guanidinium counter-ions, which themselves display hydrogen bonding to two symmetry-related 2-(myristoylthio)ethanesulfonate ions. Thus each cation forms six N—H...O bonds to neighboring anions, thereby self-assembling an extended ladder-type network. The average hydrogen-bond donor–acceptor distance is 2.931 (5) Å. The alkyl chains form the rungs of a ladder with hydrogen-bonding interactions forming the side rails.