Preparation and Performance Study of Boron Adsorbent from Plasma-Grafted Polypropylene Melt-Blown Fibers

Abstract

In this study, the plasma graft polymerization technique was used to graft glycidyl methacrylate (GMA) onto polypropylene (PP) melt-blown fibers, which were subsequently aminated with N-methyl-D-glucamine (NMDG) by a ring-opening reaction, resulting in the formation of a boron adsorbent denoted as PP-g-GMA-NMDG. The optimal conditions for GMA concentration, grafting time, grafting temperature, and the quantity of NMDG were determined using both single factor testing and orthogonal testing. These experiments determined the optimal process conditions to achieve a high boron adsorption capacity of PP-g-GMA-NMDG. Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), energy dispersion spectrum analysis (EDS), and water contact angle measurements were performed to characterize the prepared adsorbent. Boron adsorption experiments were carried out to investigate the effects of pH, time, temperature, and boron concentration on the boron adsorption capacity of PP-g-GMA-NMDG. The adsorption isotherms and kinetics of PP-g-GMA-NMDG for boron were also studied. The results demonstrated that the adsorption process followed a pseudo-second-order kinetic model and a Langmuir isothermal model. At a pH of 6, the maximum saturation adsorption capacity of PP-g-GMA-NMDG for boron was 18.03 ± 1 mg/g. In addition, PP-g-GMA-NMDG also showed excellent selectivity for the adsorption of boron in the presence of other cations, such as Na+, Mg2+, and Ca2+, PP-g-GMA-NMDG, and exhibited excellent selectivity towards boron adsorption. These results indicated that the technique of preparing PP-g-GMA-NMDG is both viable and environmentally benign. The PP-g-GMA-NMDG that was made has better qualities than other similar adsorbents. It has a high adsorption capacity, great selectivity, reliable repeatability, and easy recovery. These advantages indicated that the adsorbents have significant potential for widespread application in the separation of boron in water.

Keywords

• plasma graft polymerization
• PP melt-blown fibers
• boron
• adsorption