Magnetic properties of glass-ceramics obtained by crystallization of iron-rich borosilicate glasses

Abstract

Abstract The specific dynamic magnetic response and magnetic relaxation phenomena in magnetite-based glass-ceramics by controlled crystallization of Fe-rich borosilicate glasses with 25 wt% Fe2O3, in the presence of two types of nucleating agents, Cr2O3 and P2O5, were investigated. The magnetic response is complex and shows contributions arising from two subsystems: a system with collective characteristics, superspin-glass like, and another one with single particle characteristics (superparamagnetic) with dipolar interaction. The nucleating agents have strong influence on the characteristic temperatures and anisotropy energy.

Keywords

• magnetite
• glass-ceramics
• AC susceptibility
• magnetic relaxation
• nucleating agent