A Simple and Selective Nanocatalytic Resonance Rayleigh Scattering Spectral Method for the Determination of Trace Re

Shengmian Wang; Guiqing Wen; Tingsheng Li; Xianjiu Liao; Aihui Liang; Zhiliang Jiang

doi:10.1155/2013/646050

Journal of Spectroscopy (Jan 2013)

A Simple and Selective Nanocatalytic Resonance Rayleigh Scattering Spectral Method for the Determination of Trace Re

Shengmian Wang,
Guiqing Wen,
Tingsheng Li,
Xianjiu Liao,
Aihui Liang,
Zhiliang Jiang

Affiliations

Shengmian Wang: Key Laboratory of Ecology of Rare and Endangered Species and Environmental Protection of Ministry of Education, Guangxi Normal University, Guilin 541004, China
Guiqing Wen: Key Laboratory of Ecology of Rare and Endangered Species and Environmental Protection of Ministry of Education, Guangxi Normal University, Guilin 541004, China
Tingsheng Li: Key Laboratory of Ecology of Rare and Endangered Species and Environmental Protection of Ministry of Education, Guangxi Normal University, Guilin 541004, China
Xianjiu Liao: Key Laboratory of Ecology of Rare and Endangered Species and Environmental Protection of Ministry of Education, Guangxi Normal University, Guilin 541004, China
Aihui Liang: Key Laboratory of Ecology of Rare and Endangered Species and Environmental Protection of Ministry of Education, Guangxi Normal University, Guilin 541004, China
Zhiliang Jiang: Key Laboratory of Ecology of Rare and Endangered Species and Environmental Protection of Ministry of Education, Guangxi Normal University, Guilin 541004, China

DOI: https://doi.org/10.1155/2013/646050
Journal volume & issue: Vol. 2013

Abstract

Read online

In the HCl medium, rhenium (VII) or Re nanoparticles exhibited strong catalytic effect on the slow Te particle reaction between Te(VI) and Sn(II) at 70°C. The product of formed Te particles shows two strong resonance Rayleigh scattering peaks at 778 nm and 540 nm. The RS intensity at 778 nm enhanced linearly with Re concentration. The enhanced RS intensity was linear Re concentration in the range of 0.01–2.0 nmol·L−1, with a detection limit of 0.005 nmol·L−1 Re. This method was applied to the analysis of Re in ore sample, and the results were in agreement with that of the spectrophotometry.

Published in Journal of Spectroscopy

ISSN: 2314-4920 (Print); 2314-4939 (Online)
Publisher: Hindawi Limited
Country of publisher: United Kingdom
LCC subjects: Science: Physics: Optics. Light
Website: https://onlinelibrary.wiley.com/journal/9169

About the journal