Highly Efficient Wideband Microwave Absorbers Based on Zero-Valent Fe@<i>γ</i>-Fe₂O₃ and Fe/Co/Ni Carbon-Protected Alloy Nanoparticles Supported on Reduced Graphene Oxide

Abstract

Electronic systems and telecommunication devices based on low-power microwaves, ranging from 2 to 40 GHz, have massively developed in the last decades. Their extensive use has contributed to the emergence of diverse electromagnetic interference (EMI) phenomena. Consequently, EMI shielding has become a ubiquitous necessity and, in certain countries, a legal requirement. Broadband absorption is considered the only convincing EMI shielding solution when the complete disappearance of the unwanted microwave is required. In this study, a new type of microwave absorber materials (MAMs) based on reduced graphene oxide (rGO) decorated with zero-valent Fe@γ-Fe2O3 and Fe/Co/Ni carbon-protected alloy nanoparticles (NPs) were synthesized using the Pechini sol-gel method. Synthetic parameters were varied to determine their influence on the deposited NPs size and spatial distribution. The deposited superparamagnetic nanoparticles were found to induce a ferromagnetic resonance (FMR) absorption process in all cases. Furthermore, a direct relationship between the nanocomposites’ natural FMR frequency and their composition-dependent saturation magnetization (Ms) was established. Finally, the microwave absorption efficiency (0.4 MHz to 20 GHz) of these new materials was found to range from 60% to 100%, depending on the nature of the metallic particles grafted onto rGO.

Keywords

• magnetic nanoparticles
• reduced graphene oxide
• nanocomposites
• microwave absorbing materials
• electromagnetic interference shielding