A Study on the Kinetics and Effects of Three Combustion Fuels on Retort Carbonization of Corn Husk and Cob

Abstract

The drive to move away from fossil fuels and related products has drawn significant attention to biomass and biomass-related products in recent times. This study reports the effect of three forest biomass sources namely acacia auriculiformis, terminalia randii, and delonix regia as combustion fuels in a retort heated, low-temperature and top-lit updraft gasifier on biochars produced from two agricultural wastes: corn husk and corn cob. The combustion fuels were characterized using Thermogravimetric/Differential thermogravimetric analysis. Their TGA data were fitted to 16 kinetic models using the Coats-Redfern method. Characterization of the products was performed using Scanning Electron Microscopy/Energy Dispersive X-ray Spectroscopy and Fourier Transform Infra-Red Spectroscopy. Results revealed similar decomposition trends for combustion fuels. Different kinetic models predicted decomposition mechanisms of combustion fuels for the regions considered. Negative correlation was found between biochar yields and increasing carbonization temperatures with yields ranging from 64.6-37.8 % and 28.4-24.5% for corn husk and cob, respectively. Results indicate similar effects of combustion fuels on functional groups contained in biochar samples.

Keywords

• coats-redfern
• biochar
• tga
• kinetic models