Acta Crystallographica Section E (Jul 2011)

5-(1H-Indol-3-ylmethylidene)-2,2-dimethyl-1,3-dioxane-4,6-dione

  • Yu-Xin He,
  • Jin-Wei Wu,
  • Rong-Sheng Tong,
  • Jin-Qi Li,
  • Jian-You Shi

DOI
https://doi.org/10.1107/S1600536811023944
Journal volume & issue
Vol. 67, no. 7
pp. o1835 – o1835

Abstract

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In the title compound, C15H13NO4, the conjugated double-bond system between the two rings adopts a cis configuration and there is an intramolecular indole–ketone C—H...O interaction. The indole N—H group forms an intermolecular hydrogen bond with a ketone O-atom acceptor, giving a chain structure along the ab direction. The O-heterocyclic ring adopts a boat conformation and makes a dihedral angle of 16.72 (6)° with the indole ring system.