Pore-optimized MOF-808 made through a facile method using for fabrication of high-performance mixed matrix composite CO2 capture membranes

Chaoqi Ge; Menglong Sheng; Ye Yuan; Fei Shi; Yi Yang; Song Zhao; Jixiao Wang; Zhi Wang

Carbon Capture Science & Technology (Mar 2024)

Pore-optimized MOF-808 made through a facile method using for fabrication of high-performance mixed matrix composite CO2 capture membranes

Chaoqi Ge,
Menglong Sheng,
Ye Yuan,
Fei Shi,
Yi Yang,
Song Zhao,
Jixiao Wang,
Zhi Wang

Affiliations

Chaoqi Ge: Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China; Tianjin Key Laboratory of Membrane Science and Desalination Technology, Haihe Laboratory of Sustainable Chemical Transformations, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), State Key Laboratory of Chemical Engineering, Tianjin University, Tianjin 300350, China
Menglong Sheng: Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China; Tianjin Key Laboratory of Membrane Science and Desalination Technology, Haihe Laboratory of Sustainable Chemical Transformations, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), State Key Laboratory of Chemical Engineering, Tianjin University, Tianjin 300350, China
Ye Yuan: Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China; Tianjin Key Laboratory of Membrane Science and Desalination Technology, Haihe Laboratory of Sustainable Chemical Transformations, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), State Key Laboratory of Chemical Engineering, Tianjin University, Tianjin 300350, China
Fei Shi: Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China; Tianjin Key Laboratory of Membrane Science and Desalination Technology, Haihe Laboratory of Sustainable Chemical Transformations, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), State Key Laboratory of Chemical Engineering, Tianjin University, Tianjin 300350, China
Yi Yang: Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China; Tianjin Key Laboratory of Membrane Science and Desalination Technology, Haihe Laboratory of Sustainable Chemical Transformations, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), State Key Laboratory of Chemical Engineering, Tianjin University, Tianjin 300350, China
Song Zhao: Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China; Tianjin Key Laboratory of Membrane Science and Desalination Technology, Haihe Laboratory of Sustainable Chemical Transformations, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), State Key Laboratory of Chemical Engineering, Tianjin University, Tianjin 300350, China
Jixiao Wang: Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China; Tianjin Key Laboratory of Membrane Science and Desalination Technology, Haihe Laboratory of Sustainable Chemical Transformations, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), State Key Laboratory of Chemical Engineering, Tianjin University, Tianjin 300350, China
Zhi Wang: Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China; Tianjin Key Laboratory of Membrane Science and Desalination Technology, Haihe Laboratory of Sustainable Chemical Transformations, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), State Key Laboratory of Chemical Engineering, Tianjin University, Tianjin 300350, China; Corresponding author at: Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Yaguan Road 135#, Jinnan District, Tianjin, 300350, PR China

Journal volume & issue: Vol. 10
p. 100156

Abstract

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Mixed matrix composite membranes (MMCMs) are considered as one of the potential directions for the development of CO2 capture membranes. Nevertheless, the high cost and the challenging nature of improving separation performance are significant obstacles that prevent MMCMs from being widely applied in practice. In this study, we developed a cost-effective modified pore-optimized MOF-808 (MOF-808@PVAm) and utilized it to fabricate high-performance CO2 capture MMCMs. Specifically, MOF-808 and polyvinylamine (PVAm) were cross-linked by γ-(2,3-epoxypropoxy) propytrimethoxysilane (KH-560), which improved the pore structure characteristics of MOF-808 and led to high-performance MMCMs. For 2 bar feed gas (CO2/N2, 15/85), the MMCM with 33.33 wt.% MOF-808@PVAm loading displayed remarkable CO2 permeance of 2753 GPU and selectivity of 181. The prepared MMCM demonstrated good operational stability in simulated flue gas and exhibited potential for application in various gas purification fields (CO2/CH4, CO2/H2) through gas permeation tests.

Published in Carbon Capture Science & Technology

ISSN: 2772-6568 (Online)
Publisher: Elsevier
Country of publisher: United Kingdom
LCC subjects: Technology: Environmental technology. Sanitary engineering
Website: https://www.journals.elsevier.com/carbon-capture-science-and-technology

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