Synthetic Studies on Optically Active Schiff-base Ligands Derived from Condensation of 2-Hydroxyacetophenone and Chiral Diamines

Abstract

Three optically active Schiff-base ligands have been prepared by condensation of 2-hydroxyacetophenone with (1R,2R)-(-)-1,2-diaminocyclohexane, (1S,2S)-(-)-1,2-diphenylethylenediamine or R-(+)-2,2’-diamino-1,1’-binaphthalene, respectively. The products have been characterized by their IR, 1H- and 13C-NMR spectra.

Keywords

• Schiff-base
• ligands
• 2-hydroxyacetophenone
• chiral diamines