Acta Crystallographica Section E (Feb 2008)

Diaquabis(9-oxo-4,5-diazafluoren-3-olato-κ2N4,O3)cadmium(II)

  • Yun-Zheng Ding,
  • Lian-Xi Sheng,
  • Wei-Chao Qin,
  • Xing Yuan,
  • Ya-Hui Zhao

DOI
https://doi.org/10.1107/S1600536807067323
Journal volume & issue
Vol. 64, no. 2
pp. m266 – m266

Abstract

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The title compound, [Cd(C11H5N2O2)2(H2O)2], is a mononuclear complex consisting of a CdII atom, two 3-hydroxy-4,5-diazafluoren-9-one ligands and two coordinated water molecules. The CdII atom, lying on a twofold axis, displays a distorted octahedral coordintion. Adjacent molecules are linked by O—H...O hydrogen bonds and π–π interactions [centroid–centroid distance = 3.84 (1) Å], leading to a one-dimensional chain. Weak C—H...O hydrogen bonds connect the chains into a two-dimensional supramolecular structure.