Communications Chemistry (Mar 2022)
A localized view on molecular dissociation via electron-ion partial covariance
- Felix Allum,
- Valerija Music,
- Ludger Inhester,
- Rebecca Boll,
- Benjamin Erk,
- Philipp Schmidt,
- Thomas M. Baumann,
- Günter Brenner,
- Michael Burt,
- Philipp V. Demekhin,
- Simon Dörner,
- Arno Ehresmann,
- Andreas Galler,
- Patrik Grychtol,
- David Heathcote,
- Denis Kargin,
- Mats Larsson,
- Jason W. L. Lee,
- Zheng Li,
- Bastian Manschwetus,
- Lutz Marder,
- Robert Mason,
- Michael Meyer,
- Huda Otto,
- Christopher Passow,
- Rudolf Pietschnig,
- Daniel Ramm,
- Kaja Schubert,
- Lucas Schwob,
- Richard D. Thomas,
- Claire Vallance,
- Igor Vidanović,
- Clemens von Korff Schmising,
- René Wagner,
- Peter Walter,
- Vitali Zhaunerchyk,
- Daniel Rolles,
- Sadia Bari,
- Mark Brouard,
- Markus Ilchen
Affiliations
- Felix Allum
- The Chemistry Research Laboratory, Department of Chemistry, University of Oxford
- Valerija Music
- Institut für Physik und CINSaT, Universität Kassel
- Ludger Inhester
- Center for Free-Electron Laser Science CFEL, Deutsches Elektronen-Synchrotron DESY
- Rebecca Boll
- European XFEL
- Benjamin Erk
- Deutsches Elektronen-Synchrotron DESY
- Philipp Schmidt
- Institut für Physik und CINSaT, Universität Kassel
- Thomas M. Baumann
- European XFEL
- Günter Brenner
- Deutsches Elektronen-Synchrotron DESY
- Michael Burt
- The Chemistry Research Laboratory, Department of Chemistry, University of Oxford
- Philipp V. Demekhin
- Institut für Physik und CINSaT, Universität Kassel
- Simon Dörner
- Deutsches Elektronen-Synchrotron DESY
- Arno Ehresmann
- Institut für Physik und CINSaT, Universität Kassel
- Andreas Galler
- European XFEL
- Patrik Grychtol
- European XFEL
- David Heathcote
- The Chemistry Research Laboratory, Department of Chemistry, University of Oxford
- Denis Kargin
- Institut für Chemie, Universität Kassel
- Mats Larsson
- Stockholm University, AlbaNova University Center
- Jason W. L. Lee
- The Chemistry Research Laboratory, Department of Chemistry, University of Oxford
- Zheng Li
- Center for Free-Electron Laser Science CFEL, Deutsches Elektronen-Synchrotron DESY
- Bastian Manschwetus
- Deutsches Elektronen-Synchrotron DESY
- Lutz Marder
- Institut für Physik und CINSaT, Universität Kassel
- Robert Mason
- The Chemistry Research Laboratory, Department of Chemistry, University of Oxford
- Michael Meyer
- European XFEL
- Huda Otto
- Institut für Physik und CINSaT, Universität Kassel
- Christopher Passow
- Deutsches Elektronen-Synchrotron DESY
- Rudolf Pietschnig
- Institut für Chemie, Universität Kassel
- Daniel Ramm
- Deutsches Elektronen-Synchrotron DESY
- Kaja Schubert
- Deutsches Elektronen-Synchrotron DESY
- Lucas Schwob
- Deutsches Elektronen-Synchrotron DESY
- Richard D. Thomas
- Stockholm University, AlbaNova University Center
- Claire Vallance
- The Chemistry Research Laboratory, Department of Chemistry, University of Oxford
- Igor Vidanović
- Institut für Chemie, Universität Kassel
- Clemens von Korff Schmising
- Max Born Institute
- René Wagner
- European XFEL
- Peter Walter
- SLAC National Accelerator Laboratory
- Vitali Zhaunerchyk
- University of Gothenburg
- Daniel Rolles
- J. R. Macdonald Laboratory, Physics Department, Kansas State University
- Sadia Bari
- Deutsches Elektronen-Synchrotron DESY
- Mark Brouard
- The Chemistry Research Laboratory, Department of Chemistry, University of Oxford
- Markus Ilchen
- Institut für Physik und CINSaT, Universität Kassel
- DOI
- https://doi.org/10.1038/s42004-022-00656-w
- Journal volume & issue
-
Vol. 5,
no. 1
pp. 1 – 10
Abstract
Coincidence experiments at free-electron lasers enable time resolved site-specific investigations of molecular photochemistry at high signal rates, but isolating individual dissociation processes still poses a considerable technical challenge. Here, the authors use electron-ion partial covariance imaging to isolate otherwise elusive chemical shifts in UV-induced photofragmentation pathways of the prototypical chiral molecule 1-iodo-2-methylbutane.
