Nature Communications (Jan 2022)
Evolution of microscopic heterogeneity and dynamics in choline chloride-based deep eutectic solvents
- Stephanie Spittle,
- Derrick Poe,
- Brian Doherty,
- Charles Kolodziej,
- Luke Heroux,
- Md Ashraful Haque,
- Henry Squire,
- Tyler Cosby,
- Yong Zhang,
- Carla Fraenza,
- Sahana Bhattacharyya,
- Madhusudan Tyagi,
- Jing Peng,
- Ramez A. Elgammal,
- Thomas Zawodzinski,
- Mark Tuckerman,
- Steve Greenbaum,
- Burcu Gurkan,
- Mark Dadmun,
- Edward J. Maginn,
- Joshua Sangoro
Affiliations
- Stephanie Spittle
- Department of Chemical and Biomolecular Engineering, University of Tennessee
- Derrick Poe
- Department of Chemical and Biomolecular Engineering, University of Notre Dame
- Brian Doherty
- Department of Chemistry, New York University
- Charles Kolodziej
- Department of Chemistry, Case Western Reserve University
- Luke Heroux
- Department of Materials Science and Engineering, University of Tennessee
- Md Ashraful Haque
- Department of Chemistry, University of Tennessee
- Henry Squire
- Department of Chemical and Biomolecular Engineering, Case Western Reserve University
- Tyler Cosby
- School of Mathematics and Sciences, University of Tennessee Southern
- Yong Zhang
- Department of Chemical and Biomolecular Engineering, University of Notre Dame
- Carla Fraenza
- Department of Physics and Astronomy, Hunter College
- Sahana Bhattacharyya
- Department of Physics and Astronomy, Hunter College
- Madhusudan Tyagi
- NIST Center for Neutron Research
- Jing Peng
- School of Materials Science and Engineering, Beihang University
- Ramez A. Elgammal
- Department of Chemical and Biomolecular Engineering, University of Tennessee
- Thomas Zawodzinski
- Department of Chemical and Biomolecular Engineering, University of Tennessee
- Mark Tuckerman
- Department of Chemistry, New York University
- Steve Greenbaum
- Department of Physics and Astronomy, Hunter College
- Burcu Gurkan
- Department of Chemical and Biomolecular Engineering, Case Western Reserve University
- Mark Dadmun
- Department of Chemistry, University of Tennessee
- Edward J. Maginn
- Department of Chemical and Biomolecular Engineering, University of Notre Dame
- Joshua Sangoro
- Department of Chemical and Biomolecular Engineering, University of Tennessee
- DOI
- https://doi.org/10.1038/s41467-021-27842-z
- Journal volume & issue
-
Vol. 13,
no. 1
pp. 1 – 14
Abstract
Tailoring the macroscopic properties of deep eutectic solvents requires knowing how these depend on the local structure and microscopic dynamics. The authors, with computational and experimental tools spanning a wide range of space- and timescales, shed light into the relationship between micro and macroscopic properties in glyceline and ethaline.
