Shiyou shiyan dizhi (Sep 2023)

Progress in the study of carbonate clumped isotope in the thermal history of marine basins

  • Nansheng QIU,
  • Xin LIU,
  • Yujie XIONG,
  • Yuchen LIU,
  • Qiuchen XU,
  • Qing CHANG

DOI
https://doi.org/10.11781/sysydz202305891
Journal volume & issue
Vol. 45, no. 5
pp. 891 – 903

Abstract

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The study of thermal history of sedimentary basins is very important for oil-gas accumulation analysis and has decisive influence on oil and gas exploration and oil-gas resource evaluation. However, it is difficult to reconstruct the thermal history of carbonate strata in marine basins due to the lack of effective palaeo-thermometer. The carbonate cluster isotope is an index that can indicate the formation temperature of carbonate rock. It records temperature information in chemical bond through conjugated 13C-18O, and temperature information is revealed through changes in the abundance of conjugated 13C-18O, namely, the abundance of carbonate clumped isotope (Δ47) is closely related to the evolution of strata temperature. This paper reviews the application of carbonate clumped isotope palaeo-thermometer and discusses the existing problems and future development direction based on the basic principle and methods of carbonate clumped isotope thermometry and thermal history reconstruction, and combined with the case studies of thermal history reconstruction in marine basins in recent years. As a new palaeo-thermometer, carbonate clumped isotope shows great potential in the thermal history reconstruction of carbonate strata. Previous studies show that the maximum paleotemperature of the Bird Spring Formation in Arrow Canyon, Nevada, USA is about 175 ℃, and the maximum burial temperature of Permian Maokou Formation in the Sichuan Basin is 213-225 ℃. There is an abnormal high temperature of above 160 ℃ in the Ordovician strata of the Tarim Basin due to the Permian magmatic activity. We believe that the carbonate clumped isotope is still insufficient in the reconstruction of thermal history due to the immaturity of thermal evolution models, the recrystallization, and the change of burial temperature. Thus, we suggest that combining the carbonate clumped isotope, U-Pb dating, and other palaeo-thermometers to accurately reconstruct the thermal history of carbonate strata will be the future development direction.

Keywords