Impact of LED radiation intensity on gold nanoparticles photodeposition on TiO2 with physicochemical and photocatalytic characterization

Abstract

Abstract This study investigates the influence of LED radiation intensity on the photodeposition of gold nanoparticles onto TiO2 substrates, examining their physicochemical properties and photocatalytic activities. Utilizing a range of radiation intensities and wavelengths, TiO2-Au composites were synthesized and characterized through techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM) with energy dispersive X-ray (EDX), and X-ray photoelectron spectroscopy (XPS). The deposition process, markedly enhanced by shorter wavelengths and higher intensities, efficiently formed gold nanoparticles. This research distinctly highlights observable morphological changes in the nanoparticles; increased radiation intensity not only augmented the size but also altered their shape from spherical to hexagonal. These morphological transformations significantly improve the composites’ light absorption and catalytic properties due to the surface plasmon resonance of the gold nanoparticles. Photocatalytic assessments, using metronidazole as a model pollutant, demonstrated that composites prepared with higher LED intensities showed significantly enhanced degradation capabilities compared to those synthesized with lower intensities. The findings underscore that manipulating photodeposition parameters can critically influence the structural and functional properties of TiO2-Au composites, potentially advancing their applications in environmental remediation and solar energy utilization.

Keywords

• Titanium dioxide
• Gold nanoparticles
• Photodeposition
• LED light
• Metronidazole