Finite dimension of the ion pathway networks in conducting glasses

Abstract

In disordered materials, the ordinary understanding is that charge carriers tend to occupy energetically favorable sites known as ion-conducting channels. Many studies have revealed that the inherent fractal properties of such pathways lead to a sub-diffusive behavior. The linearity or branching of these pathways is crucial for determining how the charge carriers move. It can be thought that as the space dimensionality decreases, the average distance between the highest energy barriers along the conduction paths increases. In this study the finite dimension of those pathways is computed using an extended version of the classical Hausdorff dimension. Also, the Arrhenius behavior of the most mobile lithium ions is proved, confirming that such are responsible for conductivity behavior. The lithium ions mobility behavior in response to temperature changes and the finite dimension allowed to identify the ion diffusion regions fractal features. The reported results demonstrate that as the temperature increases the conducting channels become broadener, facilitating the transfer of electrical charge through the glassy matrix, below the transition temperature. The pathways behavior confirms the increase of the ionic conductivity when the temperature increases as it is experimentally observed.

Keywords

• ionic conducting channel
• glassy ionic conductor
• solid electrolyte