Photo-induced trifunctionalization of bromostyrenes via remote radical migration reactions of tetracoordinate boron species

Chaokun Li; Shangteng Liao; Shanglin Chen; Nan Chen; Feng Zhang; Kai Yang; Qiuling Song

doi:10.1038/s41467-022-29466-3

Nature Communications (Apr 2022)

Photo-induced trifunctionalization of bromostyrenes via remote radical migration reactions of tetracoordinate boron species

Chaokun Li,
Shangteng Liao,
Shanglin Chen,
Nan Chen,
Feng Zhang,
Kai Yang,
Qiuling Song

Affiliations

Chaokun Li: Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Province University, College of Chemistry and College of Materials Science at Fuzhou University, Fuzhou
Shangteng Liao: Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Province University, College of Chemistry and College of Materials Science at Fuzhou University, Fuzhou
Shanglin Chen: Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Province University, College of Chemistry and College of Materials Science at Fuzhou University, Fuzhou
Nan Chen: Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Province University, College of Chemistry and College of Materials Science at Fuzhou University, Fuzhou
Feng Zhang: Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Province University, College of Chemistry and College of Materials Science at Fuzhou University, Fuzhou
Kai Yang: Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Province University, College of Chemistry and College of Materials Science at Fuzhou University, Fuzhou
Qiuling Song: Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Province University, College of Chemistry and College of Materials Science at Fuzhou University, Fuzhou

DOI: https://doi.org/10.1038/s41467-022-29466-3
Journal volume & issue: Vol. 13, no. 1
pp. 1 – 12

Abstract

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Tetracoordinate boron species are common radical precursors in organic synthesis, but the boron species are discarded as by-products. Herein the authors report a strategy to incorporate both the alkyl moiety and boron species into the eventual products, yielding organoboron compounds.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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