Effect of Kaolin/TiO<sub>2</sub> Additions and Contact Temperature on the Interaction between DD6 Alloys and Al<sub>2</sub>O<sub>3</sub> Shells
Guangyao Chen,
Zheyu Cai,
Man Zhang,
Yu Liu,
Qisheng Feng,
Pengyue Gao,
Xinmei Hou,
Xiaoyan Chen,
Fei Li,
Chonghe Li
Affiliations
Guangyao Chen
State Key Laboratory of Advanced Special Steel & Shanghai Key Laboratory of Advanced Ferrometallurgy, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China
Zheyu Cai
State Key Laboratory of Advanced Special Steel & Shanghai Key Laboratory of Advanced Ferrometallurgy, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China
Man Zhang
State Key Laboratory of Advanced Special Steel & Shanghai Key Laboratory of Advanced Ferrometallurgy, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China
Yu Liu
State Key Laboratory of Advanced Special Steel & Shanghai Key Laboratory of Advanced Ferrometallurgy, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China
Qisheng Feng
State Key Laboratory of Advanced Special Steel & Shanghai Key Laboratory of Advanced Ferrometallurgy, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China
Pengyue Gao
State Key Laboratory of Advanced Special Steel & Shanghai Key Laboratory of Advanced Ferrometallurgy, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China
Xinmei Hou
Beijing Advanced Innovation Center for Materials Genome Engineering, Collaborative Innovation Center of Steel Technology, University of Science and Technology Beijing, Beijing 100083, China
Xiaoyan Chen
Shanghai Key Laboratory for High Temperature Materials and Precision Forming, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
Fei Li
Shanghai Key Laboratory for High Temperature Materials and Precision Forming, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
Chonghe Li
State Key Laboratory of Advanced Special Steel & Shanghai Key Laboratory of Advanced Ferrometallurgy, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China
In this study, the effects of kaolin and TiO2 additions on the interaction between DD6 alloys and Al2O3 shells were investigated at 1550 and 1600 °C, respectively. Through the use of optical microscopy and scanning electron microscopy, the phase composition and microstructure of the shells and the alloys were studied, and the interaction mechanism was clarified. The results indicate that the shells adding kaolin and TiO2 had a relatively weak interaction with the alloys at 1550 °C, and no significant sand adhesion could be observed. As the contact temperature was increased to 1600 °C, the alloy melt could permeate into the shells, resulting in the generation of a thick sand adhesion layer. The thicknesses of the attached layers in the alloys, which contacted the shell with kaolin and TiO2, were 120 and 220 μm, respectively. No significant chemical products could be detected in the interaction layer, meaning that only physical dissolution of the shell refractory occurred. This study provides an experimental foundation for improving shell performance and offers valuable references for further research in related fields.