Acta Crystallographica Section E (Oct 2008)

Cyclohexyldimethylammonium tetrahydroxypentaborate

  • Qiang Liang,
  • Shu-Yun Xue,
  • Guo-Ming Wang,
  • Hui Li

DOI
https://doi.org/10.1107/S1600536808028869
Journal volume & issue
Vol. 64, no. 10
pp. m1269 – m1270

Abstract

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The title compound, [C8H18N]+·[B5O6(OH)4]−, has been synthesized under mild solvothermal conditions in the presence of N,N-dimethylcyclohexylamine acting as a template. The structure consists of pentaborate [B5O6(OH)4]− anions connected through O—H...O hydrogen bonds into a three-dimensional framework, with large channels along [100], [010] and [001] directions. The [C8H18N]+ cations reside in the channels, interacting with the framework through N—H...O hydrogen bonds.