Acta Crystallographica Section E (Jan 2012)

Bis(morpholin-4-ium) tetrachloridocobalt(II)

  • Wen-Zhen Wang,
  • Rayyat Huseyn Ismayilov,
  • Gene-Hsiang Lee,
  • Yuh-Sheng Wen,
  • Shie-Ming Peng

DOI
https://doi.org/10.1107/S1600536811053128
Journal volume & issue
Vol. 68, no. 1
pp. m51 – m51

Abstract

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The title compound, (C4H10NO)2[CoCl4], is an ionic compound consisting of two protonated tetrahydro-1,4-oxazine (morpholine) cations and a [CoCl4]2− dianion. The CoII ion is in a tetrahedral coordination geometry. The cations exhibit chair-shaped conformations. A three-dimensional supramolecular architecture is formed through N—H...Cl and C—H...Cl hydrogen bonds between the dianions and the cations.