Synthesis, Photochromic and Luminescent Properties of Ammonium Salts of Spiropyrans

Abstract

New salts of photochromic indoline spiropyrans capable of reversibly responding to UV radiation were synthesized to develop light-controlled materials. Photoinduced reactions of the synthesized compounds were studied using absorption and luminescence spectroscopies, and the quantum yields of photoisomerization and other spectral and kinetic characteristics were measured. It was shown that the light sensitivity and photostability of the synthesized compounds are considerably influenced by the length of the spacer between the indole and ammonium nitrogen atoms.

Keywords

• spiropyran
• merocyanine
• photochromism
• spectral and kinetic properties
• luminescent properties
• photodegradation