Acta Crystallographica Section E (Mar 2012)

catena-Poly[bis(dibenzylammonium) [[dichloridomercurate(II)]-μ-sulfato-κ2O:O′]]

  • Philippe Guionneau,
  • Arnaud Grosjean,
  • Mouhamadou Sembene Boye,
  • Aminata Diasse-Sarr

DOI
https://doi.org/10.1107/S1600536812006927
Journal volume & issue
Vol. 68, no. 3
pp. m340 – m340

Abstract

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The structure of the title compound, (C14H16N)2[HgCl2(SO4)], consists of an infinite chain propagating along the c direction, containing HgII ions tetracoordinated by two bridging O atoms of bis-monodentate sulfate anions and two chloride ligands. In the the crystal, N—H...O hydrogen bonding between the cations and the anionic chains consolidates the packing. The crystal structure was determined from an inversion twin with approximately equal twin domains.