IUCrData (Feb 2019)

N′-[5-Acetyl-3-(4-bromophenyl)-2,3-dihydro-1,3,4-thiadiazol-2-ylidene]-5-(1H-indol-3-yl)-1-phenyl-1H-pyrazole-3-carbohydrazide dimethylformamide monosolvate

  • Gamal A. El-Hiti,
  • Bakr F. Abdel-Wahab,
  • Emad Yousif,
  • Mohammad Hayal Alotaibi,
  • Amany S. Hegazy,
  • Benson M. Kariuki

DOI
https://doi.org/10.1107/S2414314619002487
Journal volume & issue
Vol. 4, no. 2
p. x190248

Abstract

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The main molecule of the title dimethylformamide monosolvate, C28H20BrN7O2S·C3H7NO, comprises bromophenyl (A), thiadiazolyl (B), pyrazolyl (C), phenyl (D) and indolyl (E) ring systems with twist angles between the planes through neigbouring rings A/B, B/C, C/D and C/E of 33.7 (1), 14.8 (1), 60.7 (2) and 20.9 (1)°, respectively. In the crystal, the molecules are related by c-glide symmetry to form columns parallel to [001] which are linked by intermolecular N—H...O, C—H...O and C—H...Br contacts.

Keywords